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101.
Matthieu Bonnivard Francisco J. Suárez-Grau Giordano Tierra 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》2016,67(2):27
In this work, we use the homogenization theory to investigate the capability of wavy riblet patterns to influence the behaviour of a viscous flow near a ribbed boundary. Starting from perfect slip conditions on the wall, we show that periodic oscillations of wavy riblets in the lateral direction may induce a friction effect in the direction of the flow, contrary to what happens with straight riblets. Finally, we illustrate this effect numerically by simulating riblet profiles that are widely used in experimental studies: the V-shape, U-shape, and blade riblets. 相似文献
102.
Flow injection (FI) methodology, using diffuse reflectance in the visible region of the spectrum, for the analysis of nickel, precipitated in the form of dimethylglyoximate, is presented. A reflectance cell, constructed in polytetrafluoroethylene, using a LED (light emitting diode) as light source and a LDR (light dependent resistor) as detector, is described. The analytical signal (S) correlates with nickel concentration (C) between 1.6 × 10−4 and 6.6 × 10−4 mol L−1. This correlation is described by the equation S = −1.108 + 3.314 × 104C − 2.081 × 107C2 (r = 0.9996). The experimentally observed limit of detection is about 1.3 × 10−4 mol L−1, as in lower concentrations the formation of precipitate is not observed. The experimental quantitation limit is about 1.6 × 10−4 mol L−1. The mean R.S.D. (relative standard deviation) is about 2.7%. Samples containing nickel were analyzed and the results obtained in this method were compared with those of other methods using the statistical Student's t-test. 相似文献
103.
Bistri O Mazeau K Auzély-Velty R Sollogoub M 《Chemistry (Weinheim an der Bergstrasse, Germany)》2007,13(31):8847-8857
New beta-cyclodextrin (beta-CD) dimeric species have been synthesised in which the two CD moieties are connected by one or two hydrophilic oligo(ethylene oxide) spacers. Their complexation with sodium adamantylacetate (free adamantane) and adamantane-grafted chitosan (AD-chitosan) was then studied by different complementary techniques and compared with their hydrophobic counterparts that contain an octamethylene spacer. Isothermal titration calorimetry experiments have demonstrated that the use of hydrophilic spacers between the two CDs instead of aliphatic chains makes almost all of the CD cavities available for the inclusion of free adamantane. Investigation of the interaction of the CDs with AD-chitosan by viscosity measurements strongly suggests that the molecular conformation of the CD dimeric species plays a crucial role in their cross-linking with the biopolymer. The derivative doubly linked with hydrophilic arms, also called a duplex, has been shown to be a more efficient cross-linking agent than its singly bridged counterpart, referred to as a dimer. Hence, only 0.5 molar equivalents of the hydrophilic duplex with respect to adamantane was required to obtain the maximum viscosity, whereas in the case of the duplex with aliphatic spacers, the maximum viscosity was achieved with a [duplex]/[AD] ratio of about 1.7 (corresponding to a [CD]/[AD] ratio of 2.5), but with a higher value. To clarify the relationships between the molecular architecture and complexation properties, computational studies were also performed that clearly confirmed the importance of double bridging. 相似文献
104.
Pennadam SS Ellis JS Lavigne MD Górecki DC Davies MC Alexander C 《Langmuir : the ACS journal of surfaces and colloids》2007,23(1):41-49
Copolymers of N-isopropylacrylamide with a fluorescent probe monomer were grafted to branched poly(ethyleneimine) to generate polycations that exhibited lower critical solution temperature (LCST) behavior. The structures of these polymers were confirmed by spectroscopy, and their phase transitions before and after complexation with DNA were followed using ultraviolet and fluorescence spectroscopy and light scattering. Interactions with DNA were investigated by ethidium bromide displacement assays, while temperature-induced changes in structure of both polymers and polymer-DNA complexes were evaluated by fluorescence spectroscopy, dynamic light scattering, laser Doppler anemometry, and atomic force microscopy (AFM) in water and buffer solutions. The results showed that changes in polymer architecture were mirrored by variations in the architectures of the complexes and that the overall effect of the temperature-mediated changes was dependent on the graft polymer architecture and content, as well as the solvent medium, concentrations, and stoichiometries of the complexes. Furthermore, AFM indicated subtle changes in polymer-DNA complexes at the microstructural level that could not be detected by light scattering techniques. Uniquely, variable-temperature aqueous-phase AFM was able to show that changes in the structures of these complexes were not uniform across a population of polymer-DNA condensates, with isolated complexes compacting above LCST even though the sample as a whole showed a tendency for aggregation of complexes above LCST over time. These results indicate that sample heterogeneities can be accentuated in responsive polymer--DNA complexes through LCST-mediated changes--a factor that is likely to be important in cellular uptake and nucleic acid transport. 相似文献
105.
Philip Coppens Mateusz Pitak Milan Gembicky Marc Messerschmidt Stephan Scheins Jason Benedict Shin‐ichi Adachi Tokushi Sato Shunsuke Nozawa Kohei Ichiyanagi Matthieu Chollet Shin‐ya Koshihara 《Journal of synchrotron radiation》2009,16(2):226-230
A RATIO method for analysis of intensity changes in time‐resolved pump–probe Laue diffraction experiments is described. The method eliminates the need for scaling the data with a wavelength curve representing the spectral distribution of the source and removes the effect of possible anisotropic absorption. It does not require relative scaling of series of frames and removes errors due to all but very short term fluctuations in the synchrotron beam. 相似文献
106.
F. Alfaro 《Physica B: Condensed Matter》2009,404(19):3066-3069
The Kondo lattice model describes a lattice of localized spins Si interacting with the conduction electrons via a local exchange coupling J. Assuming a ferromagnetic Hund's rule coupling J>0, the model can be used to describe some itinerant magnetocaloric materials such as Gd(SixGe1-x)4, La(Fe1-xSix)13, and LaCa1-xMnxO3, which are important for magnetic refrigeration near room temperature. The localized magnetic moments are described in the model Hamiltonian by spin operators, and the conduction electrons by fermionic operators. To study the magnetocaloric effect, a uniform external magnetic field is added through a Zeeman term. By averaging the fermionic degrees of freedom, one obtains an indirect exchange coupling between spins at sites i and j, which corresponds to the RKKY interaction. The self-consistent mean value is evaluated in the effective Heisenberg Hamiltonian within the random phase approximation (RPA). The conduction electron magnetization for a given value of is obtained from the corresponding Green's functions through the equation of motion method. The pressure and doping dependence of the Curie temperature are taken into account in the evaluation of . The magnetocaloric effect is characterized by the isothermal entropy change ΔS and the adiabatic temperature change ΔTad upon magnetic field variations in the neighborhood of the ferromagnetic phase transition. The results are obtained for and compared to measurements with Gd compounds. 相似文献
107.
Matthew Weidman Santiago Palanco Matthieu Baudelet Martin C. Richardson 《Spectrochimica Acta Part B: Atomic Spectroscopy》2009,64(10):961-967
Double-Pulse Laser-Induced Breakdown Spectroscopy of iron using both Nd:YAG and TEA–CO2 lasers has been investigated to better understand mechanisms of signal enhancement. The signal dependence on the delay between the two laser pulses shows an enhanced signal when the CO2 laser pulse interacts with the sample before the Nd:YAG pulse. Signal kinetics and a simple model of sample heating by the CO2 pulse show that the enhancement during the first 700 ns is due primarily to sample heating. Images of the sample surface after ablation as well as time-integrated pictures of the plasma suggest that particles are ejected from the surface during the first microseconds after the arrival of the CO2 pulse and provide fuel for the subsequent plasma created by the Nd:YAG laser. 相似文献
108.
By Ailín Ruiz de Zárate Daniel G. Alfaro Vigo ré Nachbin Wooyoung Choi 《Studies in Applied Mathematics》2009,122(3):275-294
A higher-order strongly nonlinear model is derived to describe the evolution of large amplitude internal waves over arbitrary bathymetric variations in a two-layer system where the upper layer is shallow while the lower layer is comparable to the characteristic wavelength. The new system of nonlinear evolution equations with variable coefficients is a generalization of the deep configuration model proposed by Choi and Camassa [ 1 ] and accounts for both a higher-order approximation to pressure coupling between the two layers and the effects of rapidly varying bottom variation. Motivated by the work of Rosales and Papanicolaou [ 2 ], an averaging technique is applied to the system for weakly nonlinear long internal waves propagating over periodic bottom topography. It is shown that the system reduces to an effective Intermediate Long Wave (ILW) equation, in contrast to the Korteweg-de Vries (KdV) equation derived for the surface wave case. 相似文献
109.
In this paper, we use a simple discrete dynamical model to study integer partitions and their lattice. The set of reachable configurations of the model, with the order induced by the transition rule defined on it, is the lattice of all partitions of a positive integer, equipped with a dominance ordering. We first explain how this lattice can be constructed by an algorithm in linear time with respect to its size by showing that it has a self-similar structure. Then, we define a natural extension of the model to infinity, which we compare with the Young lattice. Using a self-similar tree, we obtain an encoding of the obtained lattice which makes it possible to enumerate easily and efficiently all the partitions of a given integer. This approach also gives a recursive formula for the number of partitions of an integer, and some informations on special sets of partitions, such as length bounded partitions. 相似文献
110.
Pouzot M Nicolai T Benyahia L Durand D 《Journal of colloid and interface science》2006,293(2):376-383
Non-linear mechanical behavior at large shear deformation was been investigated for heat-set beta-lactoglobulin gels at pH 7 and 0.1 M NaCl using both oscillatory shear and shear flow. These gels have a self-similar structure at length scales smaller than the correlation length of the gel with fractal dimension d(f)=2. Strain hardening is observed that can be well described using the model proposed by Gisler et al. [T.C. Gisler, R.C. Ball, D.A. Weitz, Phys. Rev. Let. 82 (1999) 1064] for fractal colloidal gels. The increase of the shear modulus normalized by the low strain value (G(0)) is independent of G(0). For weak gels the elasticity increases up to a factor of ten, while for strong gels the increase is very small. At higher deformation irreversible fracture occurs, which leads eventually to macroscopic failure of the gel. For weak gels formed at low concentrations the deformation at failure is about 2, independent of the shear modulus. For strong gels fracture occurs at approximately constant stress (2 x 10(3) Pa). 相似文献